Buy Dichloromethane (DCM, clear solvent) Cas 75-09-2

Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula CH₂Cl₂. This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar and miscible with many organic solvents.^[13]

Natural sources of dichloromethane include oceanic sources, macroalgae, wetlands, and volcanoes.^[14] However, the majority of dichloromethane in the environment is the result of industrial emissions. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

DCM is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C. At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products. In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

CH₄ + Cl₂ → CH₃Cl + HCl

CH₃Cl + Cl₂ → CH₂Cl₂ + HCl

CH₂Cl₂ + Cl₂ → CHCl₃ + HCl

CHCl₃ + Cl₂ → CCl₄ + HCl

The output of these processes is a mixture of chloromethane, dichloromethane, chloroform, and carbon tetrachloride as well as hydrogen chloride as a byproduct. These compounds are separated by distillation.

DCM was first prepared in 1839 by the French chemist Henri Victor Regnault (1810–1878), who isolated it from a mixture of chloromethane and chlorine that had been exposed to sunlight.

 

DCM’s volatility and ability to dissolve a wide range of organic compounds makes it a useful solvent for many chemical processes.^[13] In the past it was used to decaffeinate coffee and tea, though it has mostly been replaced by extraction using supercritical CO₂, as well as to prepare extracts of hops and other flavourings.^[16][17] Its volatility has led to its use as an aerosol spray propellant and as a blowing agent for polyurethane foams.

The chemical compound’s low boiling point allows the chemical to function in a heat engine that can extract mechanical energy from small temperature differences. An example of a DCM heat engine is the drinking bird. The toy works at room temperature.^[18] It is also used as the fluid in jukebox displays and holiday bubble lights that have a colored bubbling tube above a lamp as a source of heat and a small amount of rock salt to provide thermal mass and a nucleation site for the phase changing solvent. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

DCM (as R-30) was historically utilized as a low flammability, and non-ozone depleting refrigerant in low-pressure centrifugal chillers.^[19] It began to gaining prominence as a refrigerant after Willis Carrier began experimenting with compact radial turbo compressors around 1919.^[20]

DCM chemically welds certain plastics. For example, it is used to seal the casing of electric meters. Often sold as a main component of plastic welding adhesives, it is also used extensively by model building hobbyists for joining plastic components together. It is commonly referred to as “Di-clo”. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

It is used in the garment printing industry for removal of heat-sealed garment transfers.

DCM is used in the material testing field of civil engineering; specifically it is used during the testing of bituminous materials as a solvent to separate the binder from the aggregate of an asphalt or macadam to allow the testing of the materials.^[21]

It has been used as the principal component of various paint and lacquer strippers, although its use is now restricted in the EU and many such products now use benzyl alcohol as a safer alternative. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

Dichloromethane is widely used as a solvent in part because it is relatively inert. It does participate in reactions with certain strong nucleophiles however. tert-Butyllithium deprotonates DCM:^[22]

H₂CCl₂ + RLi → HCCl₂Li + RH

Methyllithium reacts with dichloromethane to give chlorocarbene:^{[citation needed]}

CH₂Cl₂ + CH₃Li → CHCl + CH₄ + LiCl

Although DCM is a common solvent in organic chemistry laboratories and is commonly assumed to be inert, it does react with some amines and triazoles.^[23] Tertiary amines can react with DCM to form quaternary chloromethyl chloride salts via the Menshutkin reaction.^[24] Secondary amines can react with DCM to yield an equilibrium of iminium chlorides and chloromethyl chlorides, which can react with a second equivalent of the secondary amine to form aminals.^[25] At increased temperatures, pyridines including DMAP, react with DCM to form methylene bispyridinium dichlorides.^[26] Hydroxybenzotriazole and related reagents used in peptide coupling react with DCM in the presence of triethylamine, forming acetals.^[27]

Serious health risks are associated with DCM, even though it is one of the least toxic simple chlorohydrocarbons. Its high volatility makes it an inhalation hazard.^[28][29] It can also be absorbed through the skin.^[1][30] Symptoms of acute overexposure to dichloromethane via inhalation include difficulty concentrating, dizziness, fatigue, nausea, headaches, numbness, weakness, and irritation of the upper respiratory tract and eyes. More severe consequences can include suffocation, loss of consciousness, coma, and death.^[1][30]

Although the vast majority of DCM is exhaled in its unchanged form,^[8] a small percentage of DCM is metabolized to carbon monoxide, potentially leading to carbon monoxide poisoning.^[31] Acute exposure by inhalation has resulted in optic neuropathy^[32] and hepatitis.^[33] Prolonged skin contact can result in DCM dissolving some of the fatty tissues in skin, resulting in skin irritation or chemical burns.^[34]

It may be carcinogenic, as it has been linked to cancer of the lungs, liver, and pancreas in laboratory animals.^[35] Other animal studies showed breast cancer and salivary gland cancer. Research is not yet clear as to what levels may be carcinogenic to humans.^[1][30] DCM crosses the placenta but fetal toxicity in women who are exposed to it during pregnancy has not been proven.^[36] In animal experiments, it was fetotoxic at doses that were maternally toxic but no teratogenic effects were seen.^[35]

In people with pre-existing heart problems, exposure to DCM can cause abnormal heart rhythms and/or heart attacks, sometimes without any other symptoms of overexposure.^[30] People with existing liver, nervous system, or skin problems may worsen after exposure to dichloromethane.^[10]

In many countries, products containing DCM must carry labels warning of its health risks. Concerns about its health effects have led to a search for alternatives in many of its applications.^[13][37]

In the European Union, the Scientific Committee on Occupational Exposure Limit Values (SCOEL) recommends an occupational exposure limit for DCM of 100 ppm (8-hour time-weighted average) and a short-term exposure limit of 200 ppm for a 15-minute period.^[38] The European Parliament voted in 2009 to ban the use of DCM in paint-strippers for consumers and many professionals,^[39] with the ban taking effect in December 2010.^[40]

In February 2013, the US Occupational Safety and Health Administration (OSHA) and the National Institute for Occupational Safety and Health warned that at least 14 bathtub refinishers have died since 2000 from DCM exposure. These workers had been working alone, in poorly ventilated bathrooms, with inadequate or no respiratory protection, and no training about the hazards of DCM.^[10][30][41] OSHA has since then issued a DCM standard.^[42]

On March 15, 2019, the US Environmental Protection Agency (EPA) issued a final rule to prohibit the manufacture (including importing and exporting), processing, and distribution of DCM in all paint removers for consumer use, effective in 180 days. However, it does not affect other products containing DCM, including many consumer products not intended for paint removal. On April 20, 2023, the EPA proposed a widespread ban on the production of DCM with some exceptions for military and industrial uses.^[43] On April 30, 2024, the EPA finalized a ban on most commercial uses of DCM, which mainly banned its application for stripping paint and degreasing surfaces but allowed for some remaining commercial applications, such as chemical production.^[44]

The EPA (Environmental Protection Agency) finalized a ban on most uses of dichloromethane in April 2024. This ban, which took effect on July 8, 2024, prohibits most industrial and commercial uses of the chemical, including its use in paint removers for consumer use. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

New U.S. Environmental Protection Agency (EPA) regulations under the Toxic Substances Control Act (TSCA) have significantly lowered permissible exposure limits for dichloromethane to 2 ppm TWA and 16 ppm STEL, far below OSHA’s existing standard (29 CFR 1910.1052). For remaining permitted uses, this necessitates a Workplace Chemical Protection Program (WCPP) requiring initial and periodic exposure monitoring at these much stricter levels to protect worker health. This EPA Final Rule (89 FR 39806) drives the new compliance requirements for monitoring. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

Dichloromethane is not classified as an ozone-depleting substance by the Montreal Protocol.^[45] The US Clean Air Act does not regulate dichloromethane as an ozone depleter.^[46] Dichloromethane has been classified as a very short-lived substance (VSLS). Despite their short atmospheric lifetimes of less than 0.5 year, VSLSs can contribute to stratospheric ozone depletion, particularly if emitted in regions where rapid transport to the stratosphere occurs.^[47] Atmospheric abundances of dichloromethane have been increasing in recent years. Buy Dichloromethane (DCM clear solvent) Cas 75-09-2

• Deuterated dichloromethane
• Chloromethane
• Trichloromethane
• Tetrachloromethane
• List of organic compounds
• Carbon monoxide-releasing molecules

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